Groundwater Quality Assessment: A Case of Urban Population Demography and Nutrient Enrichment in Ibadan, Southwestern Nigeria
DOI:
https://doi.org/10.26437/ajar.v10i1.717Keywords:
Assessment. contamination. groundwater. nutrient. qualityAbstract
Purpose: This study examines sulphate, nitrate, ammonia, and phosphate concentrations in groundwater found within shallow hand-dug wells around residential areas with low, medium, and high population densities in Ibadan. Furthermore, it establishes seasonal variations of nutrients in groundwater sources.
Design/ Methodology/ Approach: The city's eleven Local Government Areas [LGAs] were classified into three zones of low, medium and high-density populated areas for groundwater sample collection. From each zone, three samples were collected from the dry season and three from the rainy season from hand-dug wells [about 5m], giving 198 samples. Grab samples were collected using water samples from the wells. The groundwater samples were analysed for sulphate by turbidimetric method, nitrate by phenoldisulphonic acid method, ammonia by nesslerisation method and phosphate by ammonium molybdate-ascorbic acid method using standard procedures.
Findings: Results show sulphate, nitrate, ammonia and phosphate levels in groundwater were generally high around high-density populated areas, especially during the dry season across the eleven LGAs. Mainly, sulphate and nitrate levels exceeded the NIS 977: 2017 standards of 100mg/L and 10mg/L in Ibadan Southeast and sulphate in Ibadan Northeast at high and medium populated density areas. Statistical T-testing (p=0.05) shows a significant difference in seasonal nutrient levels for all the LGAs. A positive correlation was observed in nutrient concentrations with a depth of the groundwater source.
Practical Implications: Nutrients are among the most potent contaminants of groundwater, which poses a significant threat to human capital development and health. High levels of sulphate and nitrate in the groundwater supply can lead to poor palatability and methemoglobinemia (blue baby syndrome) in babies.
Social Implications: Public enlightenment is needed on the dangers of high groundwater nutrient concentrations and their human health implications.
Originality and Value: This study provides much-needed data on groundwater nutrient levels since other available data centres focus primarily on trace metals and organics in groundwater within the Ibadan city demography.
References
Adeniran, A. (2018). Assessment of water quality in slum areas of Ibadan. Hydrology. Current
Research, 9, 1-8.
Akanbi, O.A. (2018). Hydrological characterization and prospect of basement aquifers of Ibadan
region, southwestern Nigeria. Applied Water Science, 8, 89-109.
APHA, AWWA, WEF. Standard methods for the examination of water and wastewater.
Washington DC: American Public Health Association; 2012.
Basu, A., Saha, D., Saha, R., Ghosh, T., & Saha, B. (2014). A review on sources, toxicity, and
remediation technologies for removing arsenic from drinking water. Research Chemistry Intermediation, 40, 447–485.
Etim, E. U. (2017). Occurrence and Distribution of Arsenic, Antimony and Selenium in Shallow
Groundwater Systems of Ibadan Metropolis, Southwestern Nigeria. Journal of Health and Pollution, Vol. 7, (13), 32-41.
Fabro, A.Y. R., Avila, J.G.P., Alberich, M,V.E., Sansore, S.A.C. & Camargo-Valero, M. A.
(2015). Spatial distribution of nitrate health risk associated with groundwater use as drinking water in Merida, Mexico. Applied Geography, 65, 49-57.
Fadiran, A.O., Dlamini, S.C. & Mavuso, A. (2008). A comparative study of the phosphate levels
in some surface and groundwater bodies of Swaziland. Bulletin of the Chemical Society of Ethiopia, 22(2), 197-206.
Fagbami, A. A, & Shogunle, E.AA. (1995). Soil Brief Nigeria 1: Sandy references soils of the
moist lowlands near Ibadan (Oyo State). University of Ibadan: Ibadan, and International Soil Reference and Information Centre, Wageningen. 1995 Sept; p. 19. Available from: http://www.isric.org/content/nigeria-sandy-reference-soils-moist-lowlands-near-ibadan-oyo-state.
FAO, (1997). Food and Agricultural Organization. Chemical analysis manual for food and water.
FAO, Rome. 1(2), 20-26.
Federal Republic of Nigeria. Legal notice on publication of 2006 census final results Official
Gazette. 2009. 96 (2), B1-42.
Fewtrell, I. (2004). Drinking-water nitrate, methemoglobinemia, and global burden of disease: A
discussion. Environmental Health Perspective, 112, 1371-1374.
Ganiyu, S.A., Oyadeyi, A.T., & Adeyemi, A.A. (2021). Assessment of heavy metal contamination
and associated risk in shallow groundwater sources from three different residential areas within Ibadan metropolis, southwest Nigeria. Applied Water Resources, 11, 81-89.
He, S., & Wu, J. (2019a). Hydrogeochemical characteristics, groundwater quality and health risks
from hexavalent chromium and nitrate in groundwater of Huanhe Formation in Wuqi County, northwest China. Expo Health, 11:125–137.
He, X., Wu, J., & He, S. (2019b). Hydrochemical characteristics and quality evaluation of
groundwater in terms of health risks in Luohe aquifer in Wuqi County of the Chinese Loess Plateau, northwest China. Human Ecological Risk Assessment, 25, 32–51.
International Association of Hydrogeologists (2020). Groundwater-more about the hidden
resource. https://iah.org/education/gener al-public/groundwater-hidden-resource. Accessed 13 Nov 2020.
IPIS-Integrated Risk Information System. USEPA (2012). Nitrate (CASRN 14797-55-8).
http://www.epa.gov/iris/subst/0076.htm. Accessed May 2023.
Ji. Y., Wu, J., Wang, Y., Elumalai, V., & Subramani, T. (2020). Seasonal variation of drinking
water quality and human health risk assessment in Hancheng City of Guanzhong Plain, China. Expo Health, 12, 469–485.
Jolly, S.C. (2005). Official standardized and recommended methods of analysis. Society of
Analytical Chemistry. Analytical Methods Committee of the Society for Analytical Chemistry, London. 1963.
Karunanidhi, D., Aravinthasamy, P., Subramani, T., Wu, J., & Srinivasamoorthy, K. (2019).
Potential health risk assessment for fuoride and nitrate contamination in hard rock aquifers of Shanmuganadhi River basin, South India. Human Ecological Risk Assessment, 25, 250–270.
Li, P. (2020). To make the water safer. Expo Health, 12, 337–342.
Li, P., Tian, R., Xue, C., & Wu, J. (2017). Progress opportunities and key fields for groundwater
quality research under the impacts of human activities in China with a special focus on western China. Environmental Science Pollution Research, 24, 13224–13234.
Li, P., Karunanidhi, D., Subramani, T., & Srinivasamoorthy, K. (2021). Sources and consequences
of groundwater contamination. Archives of Environmental Contamination and Toxicology, 80, 1–10.
Martínez, D., Moschione, E., Bocanegra, E., Glok Galli, M., & Aravena, R. (2014). Distribution
and origin of nitrate in groundwater in an urban and suburban aquifer in Mar del Plata, Argentina. Environmental earth sciences, 72, 1877-1886.
Mthembu, P.P., Elumalai, V., Brindha, K., & Li, P. (2020). Hydrogeochemical processes and trace
metal contamination in groundwater: impact on human health in the Maputaland coastal aquifer, South Africa. Expo Health, 12, 403–426.
Ololade, I.A., Arogunrerin, I.A., Oladoja, N.A., Ololade, O.O., & Alabi, A.B. (2021).
Concentrations and toxic equivalency of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyl (PCB) congeners in groundwater around waste dumpsites in South-West Nigeria. Archives of Environmental Contamination and Toxicology, 80,11–19.
Oloruntoba, E.O., & Ogunbunmi, T.O. (2020). Impact of informal auto-mobile mechanic
workshop activities on groundwater quality in Ibadan, Nigeria. Journal of Water Resources and Protection, 12, 590-606.
Sa'id, M. D., & Mahmud, A. M. (2013). Spectrophotometric determination of nitrate and phosphate
levels in drinking water samples in the vicinity of irrigated farmlands of Kura Town, Kano State-Nigeria. ChemSearch Journal, 4(1), 47-50.
Subba-Rao, N., Ravindra, B., & Wu, J. (2020). Geochemical and health risk evaluation of fuoride
rich groundwater in Sattenapalle Region, Guntur district, Andhra Pradesh, India. Human Ecological Risk Assessment, 26, 2316–2348.
Umezawa, Y., Hosono, T., Onodera, S., Siringan, S.B., Delinom, R., Yoshimizu, C., Tayasu, I.,
Nagata, T., & Taniguchi, M. (2008). Sources of nitrate and ammonium contamination in groundwater under developing Asian Magacities. Science of the Total Environment, 404, 361-376.
USEPA (2001). Risk assessment guidelind for superfund: Volume III-part A, process for
conducting probabilistic risk assessment. Washington D.C. United States Environmental Protection Agency.
USEPA Region 6 (2005). Human health risk assessment protocol
http://www.epa.gov/osw/hazard/tsd/td/combust/finalmact/ssra/05hhrap7.pdf. Accessed May 2023.
USEPA (2013). Integrated risk information system (IRIS). Washington D.C. United State
Environmental Protection Agency.
Van Maanen, J.M., Albering, H.J., De Kok, T.M., Van Breda, S.G., Curfs, D.M., Vermeer, I.T.,
Ambergen, A.W., Wolffenbuttel, B.H., Kleinjans, J.C., & Reeser, H.M. (2000). Does the risk of childhood diabetes mellitus require revision of the guideline values for nitrate in drinking water? Environmental Health Perspective, 108(5), 457–461.
Wu, J., Zhang, Y., & Zhou, H. (2020). Groundwater chemistry and groundwater quality index
incorporating health risk weighting in Dingbian County, Ordos basin of northwest China. Geochemistry, 80(4), 125607.
Downloads
Published
How to Cite
Issue
Section
Categories
License
Copyright (c) 2024 AFRICAN JOURNAL OF APPLIED RESEARCH
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
By submitting and publishing your articles in the African Journal of Applied Research, you agree to transfer the copyright of the Article from the authors to the Journal ( African Journal of Applied Research).